Isolation and characterisation of iron(II) complexes with dinitrogen, and of other derivatives, especially from phenylacetylene

David L. Hughes; G. Jeffery Leigh; Manuel Jimenez-Tenorio; Adrian T. Rowley

doi:10.1039/DT9930000075

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Isolation and characterisation of iron(II) complexes with dinitrogen, and of other derivatives, especially from phenylacetylene

David L. Hughes, G. Jeffery Leigh, Manuel Jimenez-Tenorio and Adrian T. Rowley

Abstract

The complex [FeCl₂(dmpe)₂](dmpe = Me₂PCH₂CH₂PMe₂) dissolves in alcohols under dinitrogen to yield the dinitrogen complex [FeCl(N₂)(dmpe)₂]⁺. Reactions of [FeCl₂(dmpe)₂] with PhC [triple bond, length half m-dash] CH yield the interconvertible acetylide and vinylidene complexes [FeCl(CCPh)(dmpe)₂] and [FeCl(C [double bond, length half m-dash] CHPh)(dmpe)₂]⁺, the structures of which have been determined. Related complexes of Et₂PCH₂CH₂PEt₂ have been prepared, as well as similar complexes containing ligands such as MeNC, CO, etc.

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DOI: https://doi.org/10.1039/DT9930000075
Article type: Paper

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J. Chem. Soc., Dalton Trans., 1993, 75-82

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Isolation and characterisation of iron(II) complexes with dinitrogen, and of other derivatives, especially from phenylacetylene

D. L. Hughes, G. J. Leigh, M. Jimenez-Tenorio and A. T. Rowley, J. Chem. Soc., Dalton Trans., 1993, 75 DOI: 10.1039/DT9930000075

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Journal of the Chemical Society, Dalton Transactions

Isolation and characterisation of iron(II) complexes with dinitrogen, and of other derivatives, especially from phenylacetylene

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Isolation and characterisation of iron(II) complexes with dinitrogen, and of other derivatives, especially from phenylacetylene

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