Of all three n-butenes (but-1-ene, cis-but-2-ene and trans-but-2-ene) only the trans-isomer can easily access the pore system of the molecular sieve SAPO-17 resulting in appreciable adsorption and allowing a promising adsorptive separation of stereoisomeric butenes at temperatures of 330–395 K, where catalytic reactions do not occur.
M. Richter, U. Roost and U. Lohse, J. Chem. Soc., Chem. Commun., 1993, 1616 DOI: 10.1039/C39930001616
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