Rates of Z-philic reactions in β-substituted α-bromosulfones have been measured; for displacement–protonation ρ*= 2.9, and isotope fractionation factors close to 2.4 demonstrate extensive C-protonation in the transition structure.
A. Vernon and C. J. M. Stirling, J. Chem. Soc., Chem. Commun., 1993, 1609 DOI: 10.1039/C39930001609
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