A high selectivity of iron(III) phosphate-based catalysts in the oxidation of methanol to formaldehyde has been established and explained on the basis of the high covalency of the P–O bonds.
D. Klissurski, V. Rives, N. Abadzhjieva, Y. Pesheva, P. Pomonis, T. Sdoukos and D. Petrakis, J. Chem. Soc., Chem. Commun., 1993, 1606 DOI: 10.1039/C39930001606
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