High oxidation state transition metal fluorides are selective fluorinating agents for dichloromethane; those with d0; electronic configurations undergo hydrogen–fluorine exchange and metal reduction, while dn species undergo chlorine–fluorine exchange.
W. W. Dukat, J. H. Holloway, E. G. Hope, M. R. Rieland, P. J. Townson and R. L. Powell, J. Chem. Soc., Chem. Commun., 1993, 1429 DOI: 10.1039/C39930001429
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