Molecular structure of tetraphenylphosphonium tetracyanooxo(hydrogen cyanide-κN)molybdate(IV) pentahydrate: novel coordination of HCN to a MoIV centre
Abstract
The crystal structure of (PPh4)2[MoO(NCH-κN)(CN)4]·5H2O, displaying the first example of hydrogen cyanide coordinated to MoIVviathe nitrogen atom, is described.