SCHEDULED MAINTENANCE:
AM1, PM3 and ab initio6-31G* calculations indicate that Stereoselective epoxidation of the alkene 3 arises from stereoelectronic control exerted via a CF3–C bond orientated antit the alkene plane for steric reasons in contrast to a previously proposed model for epoxidation of allylic fluorides in which the F–C and alkene bonds are orientedsyn.
O. Casher, D. O'Hagan, C. A. Rosenkranz, H. S. Rzepa and N. A. Zaidi, J. Chem. Soc., Chem. Commun., 1993, 1337 DOI: 10.1039/C39930001337
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