The synthesis of sulfonated 2,2′-bis(diphenylphosphino)-1,1′-binaphthyl (binap) is reported; a rhodium complex of this ligand is the first to perform asymmetric hydrogenation in neat water with optical yields as high as those obtained in nonaqueous solvent.
K. Wan and M. E. Davis, J. Chem. Soc., Chem. Commun., 1993, 1262 DOI: 10.1039/C39930001262
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