Two novel arginine derivatives, N2-(2-carboxyethyl)arginine and N2-(2-carboxyethyl)-3-hydroxyarginine, are produced by a mutant of Streptomyces clavuligerus dclH 65, which is blocked in clavulanic acid biosynthesis, and the structures of the compounds indicate that they may be involved in clavulanic acid biosynthesis.
S. W. Elson, K. H. Baggaley, M. Fulston, N. H. Nicholson, J. W. Tyler, J. Edwards, H. Holms, I. Hamilton and D. M. Mousdale, J. Chem. Soc., Chem. Commun., 1993, 1211 DOI: 10.1039/C39930001211
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