The chromophore-binding structure of the neocarzinostatin complex is determined for the first time by two-dimensional 1H NMR spectroscopy, and reveals the elements of the specific binding and the stabilization interactions of the unstable dienediyne chromophore by the apoprotein.
T. Tanaka, M. Hirama, K. Fujita, S. Imajo and M. Ishiguro, J. Chem. Soc., Chem. Commun., 1993, 1205 DOI: 10.1039/C39930001205
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