Issue 14, 1993

Synthesis, crystal structure and homogeneous catalytic activity towards ethylene polymerisation of the spirocyclic chromium(II) siloxane [C[graphic ommitted])-µ-Na(thf)2}2](thf = tetrahydrofuran)

Abstract

The chromium(II) compound [C[graphic ommitted])-µ-Na(thf)2}2]1 has been isolated and structurally characterised; in combination with trimethylaluminium, it is a precatalyst for the polymerisation of ethene to linear polyethylene.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1993, 1132-1133

Synthesis, crystal structure and homogeneous catalytic activity towards ethylene polymerisation of the spirocyclic chromium(II) siloxane [C[graphic ommitted])-µ-Na(thf)2}2](thf = tetrahydrofuran)

M. Motevalli, M. Sanganee, P. D. Savage, S. Shah and A. C. Sullivan, J. Chem. Soc., Chem. Commun., 1993, 1132 DOI: 10.1039/C39930001132

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