Issue 12, 1993
From the journal:

Journal of the Chemical Society, Chemical Communications

Preparation and X-ray structures of tridentate (N,N,S) complexes of the diazene trarts-[PhSNC(4-MeC6H4)N[double bond, length half m-dash]NC(4-MeC6H4)NSPh] with platinum and palladium

Tristram Chivers,   Katherine McGregor  and  Masood Parvez  

Abstract

The reaction of trans-[PhSNC(MeC6H4)N[double bond, length half m-dash]NC(MeC6H4)NSPh] with (C2H4)Pt(PPh3)2 or Pd(PPh3)4 in toluene produces the complexes M{PhSNC(MeC6H4)N-NC(MeC6H4)NSPh}(PPh3)(M [double bond, length half m-dash] Pt, Pd) in which the ligand is bonded to the metal in a tridentate (N,N,S) fashion and the diazine is formally reduced to an azine.

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Article information

DOI
https://doi.org/10.1039/C39930001021
Article type
Paper

J. Chem. Soc., Chem. Commun., 1993, 1021-1023

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Preparation and X-ray structures of tridentate (N,N,S) complexes of the diazene trarts-[PhSNC(4-MeC6H4)N[double bond, length half m-dash]NC(4-MeC6H4)NSPh] with platinum and palladium

T. Chivers, K. McGregor and M. Parvez, J. Chem. Soc., Chem. Commun., 1993, 1021 DOI: 10.1039/C39930001021

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