Two epimeric 1,3,4-trideoxy-3-fluoronojirimycins are obtained through a total asymmetric synthesis starting from a non-carbohydrate precursor; two key-steps of the synthetic sequence are an intramolecular aminomercuration reaction and an oxidative demercuration process.
A. Arnone, P. Bravo, A. Donadelli and G. Resnati, J. Chem. Soc., Chem. Commun., 1993, 984 DOI: 10.1039/C39930000984
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