Issue 11, 1993
From the journal:

Journal of the Chemical Society, Chemical Communications

Stereodirecting substituent effects during enzyme-catalysed synthesis of cis-dihydrodiol metabolites of 1,4-disubstituted benzene substrates

Derek R. Boyd,   Narain D. Sharma,   Mark V. Hand,   Melanie R. Groocock,   Nuala A. Kerley,   Howard Dalton,   Jagdeep Chima  and  Gary N. Sheldrake  

Abstract

The cis-dihydrodiol enantiomer preferentially formed, by dioxygenase-catalysed oxidation of 1,4-disubstituted benzene substrates in growing cultures of Pseudomonas putida UV4, is found to be largely controlled by the relative size of the substituents.

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Article information

DOI
https://doi.org/10.1039/C39930000974
Article type
Paper

J. Chem. Soc., Chem. Commun., 1993, 974-976

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Stereodirecting substituent effects during enzyme-catalysed synthesis of cis-dihydrodiol metabolites of 1,4-disubstituted benzene substrates

D. R. Boyd, N. D. Sharma, M. V. Hand, M. R. Groocock, N. A. Kerley, H. Dalton, J. Chima and G. N. Sheldrake, J. Chem. Soc., Chem. Commun., 1993, 974 DOI: 10.1039/C39930000974

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