Electrochemical reduction of [(arene)Mn(CO)3]+ in the presence of tertiary phosphites or phosphines (L) produces [(arene)Mn(CO)2L]+via electron-transfer catalysis; [(mesitylene)Re(CO)3]+ is reduced in a two-electron chemically reversible step and does not undergo ligand substitution.
C. C. Neto, C. D. Baer, Y. K. Chung and D. A. Sweigart, J. Chem. Soc., Chem. Commun., 1993, 816 DOI: 10.1039/C39930000816
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