Issue 9, 1993

Enantiocontrolled synthesis of optically pure 5-trimethylsilyl- and 5-tributylstannyl-cyclohex-2-enones

Abstract

Optically pure 5-trimethylsilyl- and 5-tributylstannyl-cyclohex-2-enones have been prepared efficiently in an enantiocontrolled manner starting from the common chiral precursor by employing a novel palladium-mediated elimination reaction as the key step.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1993, 788-789

Enantiocontrolled synthesis of optically pure 5-trimethylsilyl- and 5-tributylstannyl-cyclohex-2-enones

S. Takano, Y. Higashi, T. Kamikubo, M. Moriya and K. Ogasawara, J. Chem. Soc., Chem. Commun., 1993, 788 DOI: 10.1039/C39930000788

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