The Co atom in CoII cobinamide is methylated by Mel in the presence of thiols (RSH) such as dithiothreitol in aqueous solution at 25 °C by a pH-independent pathway involving the reaction of Mel with the [RSHo–CoII] complex.
J. M. Pratt, M. S. A. Hamza and G. J. Buist, J. Chem. Soc., Chem. Commun., 1993, 701 DOI: 10.1039/C39930000701
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