Use of conformational restraints, induced by different ortho-substituents in 1-allyloxy- and 1-prop-2-ynyloxy-2-azidomethylbenzenes, can be employed to enhance the smooth intramolecular addition of the azide group to the unsaturated bond, followed by, in one example, removal of the conformational constraint.
B. S. Orlek, P. G. Sammes and D. J. Weller, J. Chem. Soc., Chem. Commun., 1993, 607 DOI: 10.1039/C39930000607
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