Issue 6, 1993
From the journal:

Journal of the Chemical Society, Chemical Communications

A novel heterotetranuclear [Cr2III(µ3-O)2Fe2III]8+ core and ground-state variability due to molecular spin frustration

Phalguni Chaudhuri,   Manuela Winter,   Peter Fleischhauer,   Wolfgang Haase,   Ulrich Flörke  and  Hans-Jürgen Haupt  

Abstract

The reaction of LCrIII units with FeII(salox) units, (L = 1,4,7-trimethyl-1,4,7-triazacyclononane and H2salox = salicylaldehyde oxime), produces in situ in methanol and in the presence of air, a small amount of triethylamine, NaClO4 and the dark-brown complex [L2Cr2(OMe)2O2(salox)2Fe2](ClO4)2·3H2O, which has been characterized by X-ray crystallography and magnetic susceptibility measurements and found to have a non-diamagnetic (ST≠ 0) ground state due to spin frustration.

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Article information

DOI
https://doi.org/10.1039/C39930000566
Article type
Paper

J. Chem. Soc., Chem. Commun., 1993, 566-568

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A novel heterotetranuclear [Cr2III(µ3-O)2Fe2III]8+ core and ground-state variability due to molecular spin frustration

P. Chaudhuri, M. Winter, P. Fleischhauer, W. Haase, U. Flörke and H. Haupt, J. Chem. Soc., Chem. Commun., 1993, 566 DOI: 10.1039/C39930000566

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