Utilising the preferential adoption of hydroxy–cyano hydrogen bond over the hydroxy–hydroxy hydrogen bond in molecular crystals, the crystal structure of 4′-cyano-2,6-dimethyl-4-hydroxyazobenzene is designed into an acentric space group.
J. A. R. P. Sarma, M. S. K. Dhurjati, K. Bhanuprakash and K. Ravikumar, J. Chem. Soc., Chem. Commun., 1993, 440 DOI: 10.1039/C39930000440
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