Unprecedented kinetic resolution of (±)-cyclohex-1-enylsilanols 1 by the Sharpless asymmetric epoxidation has been accomplished, the rate difference between enantiomers, krel, being >11 to give enantiomerically pure cyclohex-1-enylcyclohexylmethylsilanol 1b in a particular case.
K. Yamamoto, Y. Kawanami and M. Miyazawa, J. Chem. Soc., Chem. Commun., 1993, 436 DOI: 10.1039/C39930000436
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