Dinuclear ruthenium(II) complexes have been prepared which contain back-to-back bis-terpyridine ligands of various lengths (Ru ⋯ Ru distances between 7 and 20 Å) as bridges; significant electronic coupling is observed in mixed-valence states, even for the system with the longest separation.
J. Collin, P. Lainé, J. Launay, J. Sauvage and A. Sour, J. Chem. Soc., Chem. Commun., 1993, 434 DOI: 10.1039/C39930000434
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