Issue 4, 1993

Novel reactions of alkynes on a coordinatively unsaturated diruthenium centre bridged by thiolate ligands. Syntheses and crystal structures of dinuclear ruthenacyclopentenyl complexes

Abstract

The coordinatively unsaturated complex [(η5-C5Me5)Ru(µ2-SPri)2Ru(η5-C5Me5)]1 reacts with C[triple bond, length half m-dash]CR {R = Tol (p-MeCe6H4) or [graphic omitted]H2} to form novel dinuclear ruthenacyclopentenyl complexes 2 and 3, respectively, both of which have been fully characterized by X-ray crystallography.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1993, 375-377

Novel reactions of alkynes on a coordinatively unsaturated diruthenium centre bridged by thiolate ligands. Syntheses and crystal structures of dinuclear ruthenacyclopentenyl complexes

M. Nishio, H. Matsuzaka, Y. Mizobe and M. Hidai, J. Chem. Soc., Chem. Commun., 1993, 375 DOI: 10.1039/C39930000375

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