A dimanganese(II) complex [Mn{HB(3,5-Pri2pz)3}(µ-OBz)3Mn(3,5-Pri2pzH)2]1 has been synthesized from a mixture of [Mn(Cl){HB(3,5-Pri2pz)3}], 3,5-Pri2pzH, MnCl2·4H2O and NaOBz;X-ray analysis establishes the unsymmetric coordination environment of each manganese ion with a structurally unique bridging unit consisting of three carboxylate groups.
M. Osawa, U. P. Singh, M. Tanaka, Y. Moro-Oka and N. Kitajima, J. Chem. Soc., Chem. Commun., 1993, 310 DOI: 10.1039/C39930000310
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