The severely non-planar π-system of Cyclooctatetraene exhibits extreme ‘nonvertical’ behaviour in accepting triplet energy from a series of donors, a fact strongly supporting the proposal that ‘nonvertical’ behaviour is a consequence of single-bond torsional modes on the ground-state surface.
P. J. Forward, A. A. Gorman and I. Hamblett, J. Chem. Soc., Chem. Commun., 1993, 250 DOI: 10.1039/C39930000250
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