Polyaniline serves as a synthetic metal catalyst with reversible redox under oxygen to induce dehydrogenative and/or decarboxylative oxidation of benzylamines and 2-phenylglycine into the corresponding imines and, in combination with copper(II) chloride or iron(III) chloride, dehydrogenation of cinnamyl alcohol into cinnamaldehyde possibly due to complexation.
T. Hirao, M. Higuchi, I. Ikeda and Y. Ohshiro, J. Chem. Soc., Chem. Commun., 1993, 194 DOI: 10.1039/C39930000194
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