SCHEDULED MAINTENANCE
A tetradentate ligand, L, derived from a bowl-shaped calix[4]resorcinarene by incorporation of four phosphonite donors, has been used in the synthesis of several tetragold(I) and tetracopper(I) complexes, such as [L(AuCl)4] and [pyH]+[LCu4(µ-Cl)4(µ3-Cl)]–; the halide inclusion found for the copper complexes is unique in calixarene chemistry.
W. Xu, J. P. Rourke, J. J. Vittal and R. J. Puddephatt, J. Chem. Soc., Chem. Commun., 1993, 145 DOI: 10.1039/C39930000145
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