Methacrylamide bearing 4-tert-butyloxazolidin-2-one as a chiral auxiliary reacts with methanol in the presence of PdCl2 catalyst to give the corresponding acetal in 95% diastereoisomeric excess, and removal of the auxiliary results in the formation of chiral acetals.
T. Hosokawa, T. Yamanaka and S. Murahashi, J. Chem. Soc., Chem. Commun., 1993, 117 DOI: 10.1039/C39930000117
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