A novel dinuclear copper(II) diazacrown ether complex reduces in solution to the copper(I) state; the related mononuclear copper(II) monoazacrown ether complex undergoes reduction, when K+-ions are added.
C. F. Martens, A. P. H. J. Schenning, R. J. M. K. Gebbink, M. C. Feiters, J. G. M. van der Linden, J. Heck and R. J. M. Nolte, J. Chem. Soc., Chem. Commun., 1993, 88 DOI: 10.1039/C39930000088
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