A practical synthesis of the epoxy carboxylic acid 4, the left-hand segment of azinomycins, and its conversion into the naturally occurring amide 3 have been achieved enantioselectively.
K. Shishido, T. Omodani and M. Shibuya, J. Chem. Soc., Perkin Trans. 1, 1992, 2053 DOI: 10.1039/P19920002053
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