Issue 15, 1992

1H-tetrazole catalysed reactions of trialkyl phosphites: observation of a five-membered cyclic hydrophosphorane intermediate during the transesterification

Abstract

1H-Tetrazole-catalysed transesterification of a trialkyl phosphite with an alcohol and a 31P NMR experiment in the case of 4,4,5,5-tetramethyl-2-(3-phenylpropoxy)-1,3,2-dioxaphospholane showed the existence of the corresponding cyclic five-coordinate hydrophosphorane as an intermediate.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1992, 1879-1880

1H-tetrazole catalysed reactions of trialkyl phosphites: observation of a five-membered cyclic hydrophosphorane intermediate during the transesterification

Y. Watanabe, S. Maehara and S. Ozaki, J. Chem. Soc., Perkin Trans. 1, 1992, 1879 DOI: 10.1039/P19920001879

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