Issue 13, 1992

Reactions of 19-ethoxycarbonyl-19-demethylvincadifformine: synthesis of 19-ethoxycarbonyl-19-demethylapovincamine

Abstract

(±)-19-Ethoxycarbonyl-19-demethylapovincamine has been prepared by the oxidative rearrangement of (±)-19-ethoxycarbonyl-19-demethylvincadifformine. An attempt to prepare strem-peliopine by the reductive rearrangement of 19-ethoxycarbonyl-19-demethyl-1,2-dehydroaspidospermidine, obtained from the same starting material, was unsuccessful.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1992, 1583-1585

Reactions of 19-ethoxycarbonyl-19-demethylvincadifformine: synthesis of 19-ethoxycarbonyl-19-demethylapovincamine

A. Belattar and J. E. Saxton, J. Chem. Soc., Perkin Trans. 1, 1992, 1583 DOI: 10.1039/P19920001583

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