Agelasidine A 1 was synthesized using the [2,3]sigmatropic rearrangement of an allylic sulfinate to an allylic sulfone at low concentration. This biomimetic approach provided an efficient three-step synthesis of agelasidine A 1 from farnesol 16 in 54% overall yield.
Y. Ichikawa, T. Kashiwagi and N. Urano, J. Chem. Soc., Perkin Trans. 1, 1992, 1497 DOI: 10.1039/P19920001497
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...