The reaction of the transition-metal carbonyls, Mn2(CO)10, Fe(CO)5 or M(CO)6(M = Cr, Mo or W) with sulfur in 1, 2-dichlorobenzene yields polycrystalline MnS (alabandite), FeS2(marcarsite), and three new amorphous sulfur-rich sulfides CrS3, MoS4 and WS5.
D. A. Rice, S. J. Hibble, M. J. Almond, K. A. H. Mohammad and S. P. Pearse, J. Mater. Chem., 1992, 2, 895 DOI: 10.1039/JM9920200895
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