A re-examination of the structured near-UV electronic absorption spectrum of gaseous CH3ONO has revealed that previous assignments of the vibronic origin and of the prominent progression in the excited-state N![[double bond, length as m-dash]](https://www.rsc.org/images/entities/char_e001.gif)
O stretching vibration are insecure. An alternative assignment that is in better agreement with the observed spectra and their temperature dependence is presented.
M. Hippler and J. Pfab, J. Chem. Soc., Faraday Trans., 1992, 88, 2109 DOI: 10.1039/FT9928802109
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