Issue 14, 1992
From the journal:

Journal of the Chemical Society, Dalton Transactions

Reactivity of co-ordinated S2CPR3 ligands. Crystal and molecular structure of [Mo{η3-SC(SMe)PMe3}(CO)2(PMe3)2]I

Agustín Galindo,   Enrique Gutiérrez-Puebla,   Angeles Monge,   Miguel Angel Muñoz,   Antonio Pastor,   Caridad Ruiz  and  Ernesto Carmona  

Abstract

Treatment of [Mo(S2CPMe3)(CO)2(PMe3)2]1 with HBF4 or RI affords respectively [Mo{S2C(H)PMe3}(CO)2(PMe3)2]BF42 and [Mo{η3-SC(SR)PMe3}(CO)2(PMe3)2]I (R = Me 3a or Et 3b); an X-ray study of 3a shows that alkylation takes place at sulfur and that the resulting phosphoniodithioester ligand is trihapto (S,S′,C) bonded to molybdenum.

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/DT9920002307
Article type
Paper

J. Chem. Soc., Dalton Trans., 1992, 2307-2308

Permissions

Request permissions

Reactivity of co-ordinated S2CPR3 ligands. Crystal and molecular structure of [Mo{η3-SC(SMe)PMe3}(CO)2(PMe3)2]I

A. Galindo, E. Gutiérrez-Puebla, A. Monge, M. A. Muñoz, A. Pastor, C. Ruiz and E. Carmona, J. Chem. Soc., Dalton Trans., 1992, 2307 DOI: 10.1039/DT9920002307

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements