Issue 13, 1992
From the journal:

Journal of the Chemical Society, Dalton Transactions

Reactions of chloroform and gem-dichlorocarbons with binuclear rhodium complexes leading to functionalized methylene-bridged compounds

Miguel A. Ciriano,   Miguel A. Tena  and  Luis A. Oro  

Abstract

Chloroform and gem-dichlorocarbons CHCl2R (R = H, Ph or CO2Me) react rapidly with the binuclear basic metal complex [{Rh(µ-pz)(CNBut)2}2](pz = pyrazolate) under a three-fragment four-electron scheme to give mainly the compounds [{Rh(µ-pz)Cl(CNBut)2}2(µ-CHR)](R = Cl, H, CO2Me or Ph) and [{Rh(µ-pz)Cl(CNBut)2}2] as a side-product.

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Article information

DOI
https://doi.org/10.1039/DT9920002123
Article type
Paper

J. Chem. Soc., Dalton Trans., 1992, 2123-2124

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Reactions of chloroform and gem-dichlorocarbons with binuclear rhodium complexes leading to functionalized methylene-bridged compounds

M. A. Ciriano, M. A. Tena and L. A. Oro, J. Chem. Soc., Dalton Trans., 1992, 2123 DOI: 10.1039/DT9920002123

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