When K[B5H8] is stirred with SnClPh3 at room temperature for 12 h, it affords only the 1-(SnPh3)B5H8 isomer, for which 119Sn and 11B NMR spectra exhibit 119Sn–11B coupling, the first such observation for a pyramidal borane.
L. Barton and D. K. Srivastava, J. Chem. Soc., Dalton Trans., 1992, 1327 DOI: 10.1039/DT9920001327
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