Issue 7, 1992
From the journal:

Journal of the Chemical Society, Dalton Transactions

Crystal structures of trinuclear [{MnI2(PPhMe2)1.33}3] and tetranuclear [Mn4(µ4-O)I6(PPhMe2)4] formed by O[double bond, length as m-dash]O bond cleavage by the former

Brian Beagley,   Anthony G. Mackie,   Philomena P. Matear,   Charles A. McAuliffe,   Peter T. Ndifon  and  Robin G. Pritchard  

Abstract

The unique trinuclear complex [{MnI2(PPhMe2)1.33}3] has been prepared and its crystal structure determined. It consists of a pseudo-octahedral MnI4P2 unit sandwiched by two pseudo-tetrahedral MnI3P units held together by bridging iodines. Under controlled conditions this complex cleaves dioxygen to produce the tetranuclear complex [Mn4(µ4-O)I6(PPhMe2)4], the structure of which has also been determined.

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Article information

DOI
https://doi.org/10.1039/DT9920001301
Article type
Paper

J. Chem. Soc., Dalton Trans., 1992, 1301-1304

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Crystal structures of trinuclear [{MnI2(PPhMe2)1.33}3] and tetranuclear [Mn4(µ4-O)I6(PPhMe2)4] formed by O[double bond, length as m-dash]O bond cleavage by the former

B. Beagley, A. G. Mackie, P. P. Matear, C. A. McAuliffe, P. T. Ndifon and R. G. Pritchard, J. Chem. Soc., Dalton Trans., 1992, 1301 DOI: 10.1039/DT9920001301

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