Issue 22, 1992

A study on the elimination reaction of sulfonium polyelectrolyte precursor polymers to poly(p-phenylenevinylene)

Abstract

The dimethylsulfonium polyelectrolyte precursor polymer 1 afforded high quality poly(p-phenylenevinylene), PPV, when the sulfonium elimination was performed under acidic conditions; it is proposed that the elimination of the sulfonium group to form a vinylene unit proceeds by an E1 mechanism in the solid state.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1992, 1685-1687

A study on the elimination reaction of sulfonium polyelectrolyte precursor polymers to poly(p-phenylenevinylene)

D. A. Halliday, P. L. Burn, R. H. Friend and A. B. Holmes, J. Chem. Soc., Chem. Commun., 1992, 1685 DOI: 10.1039/C39920001685

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