Photoisomerization of the gem-dichlorobenzobicyclo[5.1.0]octenone 1(6 h, Pyrex) furnished the trans-fused cyclopropane 2 and the trans- and cis-cyclooctenes 3 and 4; single-crystal X-ray analyses defined the novel photoproduct structures.
J. L. Wood, P. J. Carroll and A. B. Smith, J. Chem. Soc., Chem. Commun., 1992, 1433 DOI: 10.1039/C39920001433
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