Issue 17, 1992
From the journal:

Journal of the Chemical Society, Chemical Communications

Unexpected catalytic and stereoselective hydroarylation of norbornene during the attempted rhodium-catalysed hydroamination of norbornene with aniline or diphenylamine

Jean-Jacques Brunet,   Denis Neibecker  and  Karine Philippot  

Abstract

The reaction of aniline (or diphenylamine) with norbornene in the presence of a catalytic system generated from [{Rh(PEt3)2Cl}2] and PhNHLi (or Ph2NLi) results in hydroarylation to yield 2-(2-aminophenyl)norbornane [or 2-(2-phenylaminophenyl)norbornane].

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Article information

DOI
https://doi.org/10.1039/C39920001215
Article type
Paper

J. Chem. Soc., Chem. Commun., 1992, 1215-1216

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Unexpected catalytic and stereoselective hydroarylation of norbornene during the attempted rhodium-catalysed hydroamination of norbornene with aniline or diphenylamine

J. Brunet, D. Neibecker and K. Philippot, J. Chem. Soc., Chem. Commun., 1992, 1215 DOI: 10.1039/C39920001215

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