Using 18O-labelling the oxidation of 5-tert-butyl-2-hydroxy-1,3,2-dioxaphosphorinane 8 and 9 with iodine-water has been shown to proceed non-stereospecifically, via a mechanism presumed to involve the formation of an iodophosphate intermediate which, under the reaction conditions, epimerises at phosphorus.
P. M. Cullis and M. Lee, J. Chem. Soc., Chem. Commun., 1992, 1207 DOI: 10.1039/C39920001207
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