The Me3Si group in β-trimethylsilyl N-aziridinylimines is able to direct the Bamford–Stevens reaction with or without rhodium acetate as catalyst to give allylic silanes as major or exclusive products.
T. K. Sarkar and B. K. Ghorai, J. Chem. Soc., Chem. Commun., 1992, 1184 DOI: 10.1039/C39920001184
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