Triethylbismuth reacts slowly with HOAr (Ar = C6F5, Ph) in refluxing toluene to yield the compounds [BiEt2OAr]∞ which are shown by single crystal X-ray diffraction to exist as chiral chain polymers in which bridging alkoxides join Et2Bi groups containing a stereoactive lone pair of electrons.
K. H. Whitmire, J. C. Hutchison, A. L. McKnight and C. M. Jones, J. Chem. Soc., Chem. Commun., 1992, 1021 DOI: 10.1039/C39920001021
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