Issue 13, 1992

Photocatalysis of metal clusters in cages: effective photoactivation of the water gas shift reaction catalysed on NaY zeolite-entrapped Pt12 and Pt9 carbonyl clusters

Abstract

Pt carbonyl clusters [Pt3(CO)6]n,2–(n= 3,4) in NaY zeolite pores are catalytically active for the water gas shift reaction (CO + H2O) at low temperatures, and exhibited effective photocatalysis for this reaction with a marked enhancement (ca. 38 times higher at 293 K) under illumination from a Xe lamp compared with the dark reaction.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1992, 962-963

Photocatalysis of metal clusters in cages: effective photoactivation of the water gas shift reaction catalysed on NaY zeolite-entrapped Pt12 and Pt9 carbonyl clusters

R. Wang, T. Fujimoto, T. Shido and M. Ichikawa, J. Chem. Soc., Chem. Commun., 1992, 962 DOI: 10.1039/C39920000962

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