Issue 13, 1992
From the journal:

Journal of the Chemical Society, Chemical Communications

The X-ray crystal structure of [Zn(PEt3)I2]2, the first 1:1 zinc(II) complex of a tertiary phosphine of low steric requirements, prepared by the reaction of unactivated zinc metal with diiodotriethylphosphorane

Neil Bricklebank,   Stephen M. Godfrey,   Charles A. McAuliffe,   Anthony G. Mackie  and  Robin G. Pritchard  

Abstract

Unactivated zinc powder reacts with R3Pl2(R[double bond, length half m-dash]Me, Et, Prn, Bun) to yield the unexpected 1 : 1 adducts of zinc(II), Zn(R3P)I2; the X-ray crystal structure of triethylphosphine complex shows it to be dimeric [Zn(PEt3)l2]2.

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Article information

DOI
https://doi.org/10.1039/C39920000944
Article type
Paper

J. Chem. Soc., Chem. Commun., 1992, 944-945

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The X-ray crystal structure of [Zn(PEt3)I2]2, the first 1:1 zinc(II) complex of a tertiary phosphine of low steric requirements, prepared by the reaction of unactivated zinc metal with diiodotriethylphosphorane

N. Bricklebank, S. M. Godfrey, C. A. McAuliffe, A. G. Mackie and R. G. Pritchard, J. Chem. Soc., Chem. Commun., 1992, 944 DOI: 10.1039/C39920000944

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