Issue 12, 1992

Synthesis and structure of the new cubane-like cluster [Fe4Te4(PEt3)4]PF6, containing only terminal phosphine ligands

Abstract

The cubane-like [Fe4Te4(PEt3)4]PF6 and the stellated octahedron [Fe6Se8(PEt3)6]PF6 clusters have been obtained by reaction of Fe(ClO4)2 with PEt3 and H2X (X = Te, Se), in the presence of PF6; a crystal structure of the tellurium derivative has been determined.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1992, 910-911

Synthesis and structure of the new cubane-like cluster [Fe4Te4(PEt3)4]PF6, containing only terminal phosphine ligands

F. Cecconi, C. A. Ghilardi, S. Midollini and A. Orlandini, J. Chem. Soc., Chem. Commun., 1992, 910 DOI: 10.1039/C39920000910

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