Irradiation of o-vinylbenzaldehyde 8 in the presence of secondary amines 9 results in N–H addition across the two chromophores to give o-ethylbenzamides 6; photolysis of o-(2-dialkylaminoethyl)benzaldehydes 5a and 5b also affords 6via photoexpulsion followed by recombination of the 8 and 9 which are formed.
S. V. Kessar, A. K. S. Mankotia and G. Gujral, J. Chem. Soc., Chem. Commun., 1992, 840 DOI: 10.1039/C39920000840
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