1,5,7-Triazabicyclo [4.4.0]dec-5-ene (TBD), a good catalyst for nitroalkanes in C–C bond forming reactions, forms a 1:1 α nitrotoluene as a substrate, as shown by a crystal structure determination.
E. van Aken, H. Wynberg and F. van Bolhuis, J. Chem. Soc., Chem. Commun., 1992, 629 DOI: 10.1039/C39920000629
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